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This preparation was made by many Proprietors, including:

  Alexander Barry
  Vair Clirehugh
  Dr. A. Coffin

It appears to me that the original was Vair Clirehugh's and all the others were imitations. In 1841, Clirehugh warned the public about Barry's infringements (View Ad). By 1870, Barclay & Co., claimed to own the rights to the words Tricopherous, Barry's Tricopherous, and Clirehugh's Tricopherous (View Ad).